Van't Hoff Factor Equation:
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The Van't Hoff factor (i) is a measure of the effect of a solute on colligative properties such as osmotic pressure, boiling point elevation, freezing point depression, and relative lowering of vapor pressure. It represents the number of particles a solute dissociates into in solution.
The calculator uses the Van't Hoff factor equation:
Where:
Explanation: The equation calculates the effective number of particles in solution, accounting for partial dissociation of electrolytes.
Details: The Van't Hoff factor is crucial for accurately predicting colligative properties in solutions containing electrolytes. It helps determine the extent of dissociation and is essential in various chemical and biological applications.
Tips: Enter the dissociation degree (α) as a value between 0 and 1, and the number of ions (n) as a positive integer. All values must be valid (0 ≤ α ≤ 1, n ≥ 1).
Q1: What does α = 1 mean?
A: α = 1 indicates complete dissociation of the solute into its ions.
Q2: What does α = 0 mean?
A: α = 0 indicates no dissociation, typical for non-electrolytes where i = 1.
Q3: What are typical values for n?
A: For NaCl, n = 2; for CaCl₂, n = 3; for AlCl₃, n = 4, etc.
Q4: When is the Van't Hoff factor not applicable?
A: The factor may not accurately predict behavior for concentrated solutions where ion pairing occurs, or for associating solutes.
Q5: How does temperature affect the Van't Hoff factor?
A: Higher temperatures generally increase dissociation (higher α values) for weak electrolytes.